Naruto Naruto in which episode did you learn spiral pills?

Episode 86. According to the query of Iqiyi app, in the 86th episode of Naruto, the spiral pill was created by Namikaze Minato, the fourth generation Naruto, and was later taught by Jiraiya to Naruto who began to learn spiral pills. Naruto is the masterpiece of Japanese cartoonist Kishimoto Masashi. It tells the story that four generations of Naruto named Kyubi no Youko fox Uzumaki and later became a ninja.